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Journal Articles Dalton Transactions Year : 2019

Transition metal-induced dehydrogenative coupling of zinc hydrides

Min Chen
  • Function : Author
Shengjie Jiang
  • Function : Author
Xin Xu
  • Function : Author

Abstract

The reaction of terminal zinc hydrides with palladium(0) species afforded an unprecedented [eta(2)-Zn2Pd] trimetallic complex through the reductive elimination of H-2. In contrast, the reaction of zinc hydrides with a nickel(0) reagent gave sigma-Zn-H coordination complexes with no direct Zn-Zn bonding. Computational studies indicated that an oxidative addition/reductive elimination process at the palladium center might be responsible for the formation of a covalent Zn-Zn bond.
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hal-04022169 , version 1 (09-03-2023)

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Min Chen, Shengjie Jiang, Laurent Maron, Xin Xu. Transition metal-induced dehydrogenative coupling of zinc hydrides. Dalton Transactions, 2019, 48 (6), pp.1931-1935. ⟨10.1039/c8dt04651d⟩. ⟨hal-04022169⟩
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