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Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN-Type Macrocyclic Ligand

Abstract : Hydrogenolysis of bis(triphenylsilyl)calcium containing the neutral NNNN‐type macrocyclic amine ligand Me4TACD [Ca(Me4TACD)(SiPh3)2] (2), gave the cationic dinuclear calcium hydride [Ca2H3(Me4TACD)2](SiPh3) (3), characterized by NMR spectroscopy, single‐crystal X‐ray analysis, and DFT calculations. Compound 3 reacted with deuterium to give the deuteride [D3]‐3.
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https://hal.insa-toulouse.fr/hal-01968880
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Submitted on : Thursday, January 3, 2019 - 2:09:45 PM
Last modification on : Tuesday, March 3, 2020 - 11:40:04 AM

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  • HAL Id : hal-01968880, version 1

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Valeri Leich, Thomas Spaniol, Laurent Maron, Jun Okuda. Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN-Type Macrocyclic Ligand. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2016, 55 (15), pp.4794-4797. ⟨hal-01968880⟩

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