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Activation of SO 2 by [Zn(Cp*) 2 ] and [(Cp*)Zn I –Zn I (Cp*)]

Abstract : Interesting reactivity was observed in reactions of SO2 with [Zn(Cp*)2] and [(Cp*)ZnI–ZnI(Cp*)]. These reactions proceeded with insertion of SO2 into the Zn–C bonds. Spectacularly, the lability of the C–S bond in the O2SCp* ligands led to the thermal decomposition of [Zn(O2SCp*)2(tmeda)] to afford [Zn2(μ-SO3)(μ-S2O4)(tmeda)2].
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Rory Kelly, Neda Kazeminejad, Carlos Lamsfus, Laurent Maron, Peter Roesky. Activation of SO 2 by [Zn(Cp*) 2 ] and [(Cp*)Zn I –Zn I (Cp*)]. Chemical Communications, Royal Society of Chemistry, 2016, 52 (89), pp.13090-13093. ⟨10.1039/c6cc05638e⟩. ⟨hal-01968877⟩

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