A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6](2+) core - INSA Toulouse - Institut National des Sciences Appliquées de Toulouse Access content directly
Journal Articles Chemical Communications Year : 2019

A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6](2+) core

Abstract

A highly symmetric, dicationic tetranuclear calcium hydride cluster with an adamantoid [Ca4H6](2+) core stabilized by the NNN macrocycle Me(3)TACN (1,4,7-trimethyl-1,4,7-triazacyclononane) was prepared. DFT calculations indicate delocalized bonding within the [Ca4H6](2+) fragment with d-orbital contribution.
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Dates and versions

hal-04022186 , version 1 (09-03-2023)

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Danny Schuhknecht, Thomas P. Spaniol, Iskander Douair, Laurent Maron, Jun Okuda. A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6](2+) core. Chemical Communications, 2019, 55 (98), pp.14837-14839. ⟨10.1039/c9cc08540h⟩. ⟨hal-04022186⟩
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