Cationic magnesium hydride [MgH](+) stabilized by an NNNN-type macrocycle - INSA Toulouse - Institut National des Sciences Appliquées de Toulouse Access content directly
Journal Articles Chemical Communications Year : 2019

Cationic magnesium hydride [MgH](+) stabilized by an NNNN-type macrocycle

Abstract

A magnesium hydride cation [(L)MgH](+) supported by a macrocyclic ligand (L = Me(4)TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclo-dodecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgH2Mg{N(SiMe3)(2)}(2)] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.

Dates and versions

hal-04022177 , version 1 (09-03-2023)

Identifiers

Cite

Lara E. Lemmerz, Debabrata Mukherjee, Thomas P. Spaniol, Anthony Wong, Gabriel Menard, et al.. Cationic magnesium hydride [MgH](+) stabilized by an NNNN-type macrocycle. Chemical Communications, 2019, 55 (22), pp.3199-3202. ⟨10.1039/c9cc00490d⟩. ⟨hal-04022177⟩
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