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Robust magnetic anisotropy of a monolayer of hexacoordinate Fe( ii ) complexes assembled on Cu(111)

Abstract : The tris pyrazolyl borate ligand imposes a rigid scaffold around Fe( ii ) ensuring a robust magnetic anisotropy when the molecules assembled as monolayers suffer from the dissymmetric environment of the substrate/vacuum interface.
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https://hal.archives-ouvertes.fr/hal-03221157
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Submitted on : Friday, May 7, 2021 - 5:55:21 PM
Last modification on : Wednesday, December 1, 2021 - 2:37:04 PM
Long-term archiving on: : Sunday, August 8, 2021 - 7:00:15 PM

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Massine Kelai, Benjamin Cahier, Mihail Atanasov, Frank Neese, Yongfeng Tong, et al.. Robust magnetic anisotropy of a monolayer of hexacoordinate Fe( ii ) complexes assembled on Cu(111). Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2021, 8 (9), pp.2395-2404. ⟨10.1039/d1qi00085c⟩. ⟨hal-03221157⟩

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